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  1. Jan 2025
  2. chem.libretexts.org chem.libretexts.org
    4.11: Many-Electron Atoms & the Periodic Table
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    1. dllahr 07 Jan 2025
      V(r12)=−e24πϵ0r12(4.11.5)

      I believe the sign of this potential energy term V(r12) [eqn. 4.11.5] should be positive, not negative (the electron-electron interaction is repulsive).

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    chem.libretexts.org/Courses/University_of_California_Davis/Chem_107B:_Physical_Chemistry_for_Life_Scientists/Chapters/4:_Quantum_Theory/4.11:_Many-Electron_Atoms_and_the_Periodic_Table