1 Matching Annotations
  1. Jul 2023
    1. The image below the following text has the energies reversed compared to the text itself. I think it was a typo in the image, as it shows the conjugated pentadiene having a greater energy release (implying a higher initial state) than the 1,4-pentadiene

      "A very important concept to keep in mind is that there is an inherent thermodynamic stability associated with conjugation. This stability can be measured experimentally by comparing the heat of hydrogenation of two different dienes. (Hydrogenation is a reaction type that we will learn much more about in chapter 15: essentially, it is the process of adding a hydrogen molecule - two protons and two electrons - to a p bond). When the two conjugated double bonds of 1,3-pentadiene are 'hydrogenated' to produce pentane, about 225 kJ is released per mole of pentane formed. Compare that to the approximately 250 kJ/mol released when the two isolated double bonds in 1,4-pentadiene are hydrogenated, also forming pentane."