Patel's hypothesis is interesting.

theory for my research

theory for my research

核心theory and hypothesis

Ce-UiO-66-F催化PMS降解SAs的中间产物 The intermediates of CUF/PMS system were identified by the HPLC-MS (in Figure S17), which was used to investigate the possible degradation pathway of sulfamethoxazole. As shown in Figure 13d, the degradation pathway of sulfamethoxazole could be summarized as hydroxylation, deamination, sulfonamide (S-N) cleavage and desulfonation. In pathway I, the isoxazole ring of sulfamethoxazole was attacked by ROSs in CUF/PMS to generate P1, P2 and P3. The breakdown products P1, P2 and P3 oxidized into P4 and P5, respectively, which was viewed as a classic oxidation pathway of sulfamethoxazole [64]. According to pathway II, the formation of P6 resulted from the oxidation of methyl group on the isoxazole ring and –NH2 on the benzene ring and then converted into P7 and P8 due to the broken S-N bond [65]. For pathway III, the S-N bond of sulfamethoxazole could be directly broken by ROSs to be mineralized into P5 and P9. Then, the isoxazole ring of TP 9 was attacked by ROSs to form P10 due to hydroxylation, and then further generated P11, caused by high reactivity between ·HO and olefinic double bonds [66]. In addition, the generated P9 was further converted into P12 via coupling reaction and electrophilic replacement of the isoxazole ring, respectively [67]. The formation of P13 might be involved in the coupling of N-centered radical derived from by –NH2 group of P10 and intermediate products [68]. Then, the isoxazole ring opening reaction occurred resulting in the generation of P14, which was oxidized by ROSs into P15. Finally, these intermediates would be further mineralized into small molecules (P16, P17 and P18). W. Peng, J. Liao, Y. Yan, L. Chen, C. Ge, S. Lin Enriched nitrogen-doped carbon derived from expired drug with dual active sites as effective peroxymonosulfate activator: Ultra-fast sulfamethoxazole degradation and mechanism insight Chem. Eng. J., 446 (2022), Article 137407, 10.1016/j.cej.2022.137407 View PDF View articleView in ScopusGoogle Scholar [65] Y. Chen, D. Chen, X. Bai Binary MOFs-derived Mn-Co3O4 for efficient peroxymonosulfate activation to remove sulfamethoxazole: Oxygen vacancy-assisted high-valent cobalt-oxo species generation Chem. Eng. J., 479 (2024), Article 147886, 10.1016/j.cej.2023.147886 View PDF View articleView in ScopusGoogle Scholar [66] Y. Bao, W.J. Lee, T.-T. Lim, R. Wang, X. Hu Pore-functionalized ceramic membrane with isotropically impregnated cobalt oxide for sulfamethoxazole degradation and membrane fouling elimination: Synergistic effect between catalytic oxidation and membrane separation Appl. Catal. B-Environ., 254 (2019), pp. 37-46, 10.1016/j.apcatb.2019.04.081 View PDF View articleView in ScopusGoogle Scholar [67] M. Xu, H. Zhou, Z. Wu, N. Li, Z. Xiong, G. Yao, B. Lai Efficient degradation of sulfamethoxazole by NiCo2O4 modified expanded graphite activated peroxymonosulfate: Characterization, mechanism and degradation intermediates J. Hazard. Mater., 399 (2020), Article 123103, 10.1016/j.jhazmat.2020.123103 View PDF View articleView in ScopusGoogle Scholar [68] R. Guo, Y. Wang, J. Li, X. Cheng, D.D. Dionysiou Sulfamethoxazole degradation by visible light assisted peroxymonosulfate process based on nanohybrid manganese dioxide incorporating ferric oxide Appl. Catal. B-Environ., 278 (2020), Article 119297, 10.1016/j.apcatb.2020.119297 View PDF View articleView in ScopusGoogle Scholar

PMS非均相催化剂吸附PMS,污染物 X. Zhou, Q. Zhao, J. Wang, Z. Chen, Z. Chen Nonradical oxidation processes in PMS-based heterogeneous catalytic system: Generation, identification, oxidation characteristics, challenges response and application prospects Chem. Eng. J., 410 (2021), Article 128312

实际用于处理废水的各种影响 X. He, K.E. O'Shea Selective oxidation of H(1)-antihistamines by unactivated peroxymonosulfate (PMS): Influence of inorganic anions and organic compounds Water Res., 186 (2020), Article 116401,

进一步探究PH的影响，电子互斥，碱活化PMS 44.X. Huang, W. Ren, X. Liu, C. Lin, M. He, W. Ouyang CuMgFe-LDO as superior peroxymonosulfate activator for imidacloprid removal: Performance, mechanism and effect of pH Chem. Eng. J., 441 (2022), Article 136135, 10.1016/j.cej.2022.136135 45.L. Hu, G. Zhang, M. Liu, Q. Wang, P. Wang Enhanced degradation of Bisphenol A (BPA) by peroxymonosulfate with Co3O4-Bi2O3 catalyst activation: Effects of pH, inorganic anions, and water matrix Chem. Eng. J., 338 (2018), pp. 300-310,

PMS建议投加量，以及测量反应速率常数K的重要性，自淬灭效应 J. Yan, H. Liu, C. Dou, Y. Wu, W. Dong Quantitative probing of reactive oxygen species and their selective degradation on contaminants in peroxymonosulfate-based process enhanced by picolinic acid

PH影响 Y. Ma, L. Yang, L. Wu, P. Li, X. Qi, L. He, S. Cui, Y. Ding, Z. Zhang Carbon nanotube supported sludge biochar as an efficient adsorbent for low concentrations of sulfamethoxazole removal

Y. Luo , S. Bag , O. Zaremba , A. Cierpka , J. Andreo , S. Wuttke , P. Friederich and M. Tsotsalas , MOF Synthesis Prediction Enabled by Automatic Data Mining and Machine Learning, Angew. Chem., Int. Ed., 2022, 61 , e202200242 通过自动数据挖掘与机器学习实现 MOF 合成预测

温度与缺陷生成明确相关，这很可能源于高温下调节剂与无机金属-氧簇之间 Zr-O 键的热诱导不稳定性。因此，较高温度对应较少缺陷，从而促进调节剂封端配体从无机簇上脱离。随后，对苯二甲酸（BDC）配体可与 Zr 节点配位，导致结构缺陷减少 42.C. S. Cox , E. Slavich , L. K. Macreadie , L. K. McKemmish and M. Lessio , Understanding the Role of Synthetic Parameters in the Defect Engineering of UiO-66: A Review and Meta-analysis, Chem. Mater., 2023, 35 , 3057 —3072 43。X. Qiu and R. Wang , From construction strategies to applications: Multifunctional defective metal-organic frameworks, Coord. Chem. Rev., 2025, 526 , 216356

这反映了不同竞争物种在缺陷调控中的协同作用，然而，竞争物种间的协同机制仍不明确。 K. Tan , H. Pandey , H. Wang , E. Velasco , K.-Y. Wang , H.-C. Zhou , J. Li and T. Thonhauser , Defect Termination in the UiO-66 Family of Metal–Organic Frameworks: The Role of Water and Modulator, J. Am. Chem. Soc., 2021, 143 , 6328 —6332

双组分调节 M. A. Artsiusheuski , N. P. M. Casati , A. H. Clark , M. Nachtegaal , R. Verel , J. A. van Bokhoven and V. L. Sushkevich , Controlling the Mechanism of Nucleation and Growth Enables Synthesis of UiO-66 Metal–Organic Framework with Desired Macroscopic Properties, Angew. Chem., Int. Ed., 2024, e202415919 40.X. Chen , Y. Lyu , Z. Wang , X. Qiao , B. C. Gates and D. Yang , Tuning Zr12O22 Node Defects as Catalytic Sites in the Metal–Organic Framework hcp UiO-66, ACS Catal., 2020, 10 , 2906 —2914

本文，查为什么单组分策略面临局限性

单组分策略 X. Feng , H. S. Jena , C. Krishnaraj , D. Arenas-Esteban , K. Leus , G. Wang , J. Sun , M. Rüscher , J. Timoshenko , B. Roldan Cuenya , S. Bals and P. V. D. Voort , Creation of Exclusive Artificial Cluster Defects by Selective Metal Removal in the (Zn, Zr) Mixed-Metal UiO-66, J. Am. Chem. Soc., 2021, 143 , 21511 —21518 CrossRef CAS PubMed . X. Feng、H. S. Jena、C. Krishnaraj、D. Arenas-Esteban、K. Leus、G. Wang、J. Sun、M. Rüscher、J. Timoshenko、B. Roldan Cuenya、S. Bals 和 P. V. D. Voort，通过选择性金属移除在 (Zn, Zr) 混合金属 UiO-66 中创建专属人工簇缺陷，《J. Am. Chem. Soc.》，2021 年，第 143 卷，第 21511—21518 页 CrossRef CAS PubMed 。Journal of The American Chemical Society化学TOPESI学科分类：化学JCI 2.64IF(5) 15.6EI检索SCI升级版 化学1区SCI基础版 化学1区SCI Q1IF 15.7 S. Yuan , J. Peng , Y. Zhang and Y. Shao-Horn , Stability Trend of Metal–Organic Frameworks with Heterometal-Modified Hexanuclear Zr Building Units, J. Phys. Chem. C, 2019, 123 , 28266 —28274 CrossRef CAS . S. Yuan, J. Peng, Y. Zhang 和 Y. Shao-Horn, 异金属修饰六核锆构筑单元对金属有机框架稳定性的影响趋势, J. Phys. Chem. C, 2019, 123, 28266—28274 CrossRef CAS 。Journal of Physical Chemistry cESI学科分类：化学JCI 0.51IF(5) 3.5EI检索SCI升级版 化学3区SCI基础版 化学2区SCI Q3IF 3.2 Y. Ma , A. Li and C. Wang , Experimental study on adsorption removal of SO2 in flue gas by defective UiO-66, Chem. Eng. J., 2023, 455 , 140687 CrossRef CAS . Y. Ma、A. Li 和 C. Wang，缺陷型 UiO-66 吸附去除烟气中 SO2 的实验研究，Chem. Eng. J.，2023，455，140687 CrossRef CAS 。

S. Zhuang and J. Wang , Adsorptive removal of pharmaceutical pollutants by defective metal organic framework UiO-66: Insight into the contribution of defects, Chemosphere, 2021, 281 , 130997 33.X. Feng , H. S. Jena , C. Krishnaraj , K. Leus , G. Wang , H. Chen , C. Jia and P. Van Der Voort , Generating Catalytic Sites in UiO-66 through Defect Engineering, ACS Appl. Mater. Interfaces, 2021, 13 , 60715 —60735

A. Jrad , G. Al Sabeh , K. Hannouche , R. Al Natour , O. Haidar , H. Sammoury , M. N. Ahmad and M. Hmadeh , Critical Role of Defects in UiO-66 Nanocrystals for Catalysis and Water Remediation, ACS Appl. Nano Mater., 2023, 6 , 18698 —18720

G. Cai , X. Ma , M. Kassymova , K. Sun , M. Ding and H.-L. Jiang , Large-Scale Production of Hierarchically Porous Metal–Organic Frameworks by a Reflux-Assisted Post-Synthetic Ligand Substitution Strategy, ACS Cent. Sci., 2021, 7 , 1434 —1440 延长配体扩展孔径的局限

26.L. Zhou , N. Li , G. Owens and Z. Chen , Simultaneous removal of mixed contaminants, copper and norfloxacin, from aqueous solution by ZIF-8, Chem. Eng. J., 2019, 362 , 628 —637 27.G. Chaturvedi , A. Kaur , A. Umar , M. A. Khan , H. Algarni and S. K. Kansal , Removal of fluoroquinolone drug, levofloxacin, from aqueous phase over iron based MOFs, MIL-100(Fe), J. Solid State Chem., 2020, 281 , 121029 28.R. Yu and Z. Wu , High adsorption for ofloxacin and reusability by the use of ZIF-8 for wastewater treatment, Microporous Mesoporous Mater., 2020, 308 , 110494 29.X. Fang , S. B. Wu , Y. H. Wu , W. Yang , Y. L. Li , J. Y. He , P. D. Hong , M. X. Nie , C. Xie , Z. J. Wu , K. S. Zhang , L. T. Kong and J. H. Liu , High-efficiency adsorption of norfloxacin using octahedral UIO-66-NH2 nanomaterials: Dynamics, thermodynamics, and mechanisms, Appl. Surf. Sci., 2020, 518 , 146226 30.H. Wang , X. Pei , M. J. Kalmutzki , J. Yang and O. M. Yaghi , Large Cages of Zeolitic Imidazolate Frameworks, Acc. Chem. Res., 2022, 55 , 707 —721

R.-R. Liang , S. Xu , Z. Han , Y. Yang , K.-Y. Wang , Z. Huang , J. Rushlow , P. Cai , P. Samorì and H.-C. Zhou , Exceptionally High Perfluorooctanoic Acid Uptake in Water by a Zirconium-Based Metal–Organic Framework through Synergistic Chemical and Physical

C. S. Diercks , M. J. Kalmutzki , N. J. Diercks and O. M. Yaghi , Conceptual Advances from Werner Complexes to Metal–Organic Frameworks, ACS Cent. Sci., 2018, 4 , 1457 —1464

Cleared some misconception!

但是南非的鸟是可以以稳定持续的groove的耶！

两个研究都可以引用

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