Svante Arrhenius in 1896. His paper, published in the Philosophical Magazine and Journal of Science, was the first to quantify the contribution of carbon dioxide to what scientists now call the "greenhouse effect."

‘Truly it would seem as if “Man strews the earth with ruin.”4 But this conclusion is too flattering to human vanity. Man's most permanent memorial is a rubbish-heap, and even that is doomed to be obliterated’ (Sherlock, 1922, p. 343

In 1873, the Italian geologist and priest Antonio Stoppani suggested that our technologies, infrastructures, and patterns of land use had created fundamental changes in Earth’s systems, propelling us into what he called an ‘anthropozoic era’